Q = ΔU + W
Q = f/2 nRΔT + PΔV
if f = 2
⇒ Q = nRΔT + PΔV
= 1 × 8.3 × 1.2 + 10⁵ × 25 × 10⁻³ × 4 × 10⁻⁴
= 10.96 (No option is matching)
if f = 5
⇒ Q = 2.5nRΔT + PΔV
=2.5 × 1 × 8.3 × 1.2 + 10⁵ × 25 × 10⁻³ × 4 × 10⁻⁴
= 25.9 (closest is 25)
Note : As PΔV ≠ nRΔT, given state is inconsistent.
Hence we can opt the most suitable option as (2).
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